Methane steam reforming in a Pd-Ag membrane reformer: An experimental study on reaction pressure influence at middle temperature

In this experimental work, methane steam reforming (MSR) reaction is performed in a dense Pd-Ag membrane reactor and the influence of pressure on methane conversion, CO_x-free hydrogen recovery and CO_x-free hydrogen production is investigated. The reaction is conducted at 450 °C by supplying nitrogen as a sweep gas in co-current flow configuration with respect to the reactants. Three experimental campaigns are realized in the MR packed with Ni-ZrO catalyst, which showed better performances than Ni-Al₂O₃ used in a previous paper dealing with the same MR system. The first one is directed to keep constant the total pressure in both retentate and permeate sides of the membrane reactor. In the second case study, the total retentate pressure is kept constant at 9.0 bar, while the total permeate pressure is varied between 5.0 and 9.0 bar. As the best result of this work, at 450 °C and 4.0 bar of total pressure difference between retentate and permeate sides, around 65% methane conversion and 1.2 l/h of CO_x-free hydrogen are reached, further recovering 80% CO_x-free hydrogen over the total hydrogen produced during the reaction. Moreover, a study on the influence of hydrogen-rich gas mixtures on the hydrogen permeation through the Pd-Ag membrane is also performed and discussed.     

Pillar-assisted epitaxial assembly of toric focal conic domains of smectic-a liquid crystals

SU-8 pillar-assisted epitaxial assembly of toric focal conic domains (TFCDs) arrays of smectic-A liquid crystals is studied. The 3D nature of the pillar array is crucial to confine and direct the formation of TFCDs on the top of each pillar and between neighboring pillars, leading to highly ordered square and hexagonal array TFCDs. Excellent agreement between the experimentally obtained critical pillar diameter and elasticity calculation is found.     

Technique based on LED multispectral imaging and multivariate analysis for monitoring the conservation state of the Dead Sea Scrolls

The aim of this project is the development of a noninvasive technique based on LED multispectral imaging (MSI) for monitoring the conservation state of the Dead Sea Scrolls (DSS) collection. It is well-known that changes in the parchment reflectance drive the transition of the scrolls from legible to illegible. Capitalizing on this fact, we will use spectral imaging to detect changes in the reflectance before they become visible to the human eye. The technique uses multivariate analysis and statistical process control theory. The present study was carried out on a "sample" parchment of calfskin. The monitoring of the surface of a commercial modern parchment aged consecutively for 2 h and 6 h at 80 °C and 50% relative humidity (ASTM) was performed at the Imaging Lab of the Library of Congress (Washington, DC, U.S.A.). MSI is here carried out in the vis-NIR range limited to 1 μm, with a number of bands of 13 and bandwidths that range from about 10 nm in UV to 40 nm in IR. Results showed that we could detect and locate changing pixels, on the basis of reflectance changes, after only a few "hours" of aging.     

Full scale experimental study of single-sided ventilation: Analysis of stack and wind effects

Natural ventilation can contribute to the reduction of the air conditioning demand and to the improvement of thermal comfort in buildings. In this paper, the flow field and the air change rate generated by a simple configuration of natural ventilation, namely single-sided ventilation, are examined experimentally. The experiments are realized in a full scale building exposed to outdoor conditions, using several measurement techniques. The main features of the flow generated by stack and wind effect are examined for different outdoor conditions (temperature difference, wind speed and direction). Finally, measured air change rates are compared to those calculated by existing correlations in order to analyze their applicability to the experimental configuration. Results show that the wind generates turbulence diffusion at the opening, counteracting the stack effect. Moreover, in the case of windward opening, there is an additional effect, namely the effect of mixing layer, which tends to increase the airflow rate. Existing correlations give reasonably good results in the case of windward opening, while in the case of leeward opening they overestimate the airflow rate.     

Some peculiarities of the diamond micro-powder sintering

Diamond micro-powders of 28/20 μm mean particle size were sintered under conditions of high pressure of 6.0 and 8.0 GPa at temperatures of 1600, 1700, and 1800 °C during various sintering times, aiming to obtain polycrystalline compacts with required strength. The experiments were carried out by using an anvil type high pressure device with toroidal concavity of 13.5 mm diameter. It was obtained samples with 4.5 mm diameter and 5.0 mm height. It was plotted the polycrystalline diamonds density dependency as a function of the process duration under the above mentioned sintering conditions. The kinetics of powder consolidation was studied by X-ray diffraction, which allowed the establishment of the correlation between the (3 3 1) plane enlargement of diamond and the structural transformations that took place during sintering. Another objective was the study of the graphitization kinetics of diamonds under the action of the sintering parameters. It was concluded that over the established consolidation mechanisms, also acts the partial shear mechanism.     

A bumpy train ride: A field experiment on insult, honor, and emotional reactions.

The present research examined the relationship between adherence to honor norms and emotional reactions after an insult. Participants were 42 Dutch male train travelers, half of whom were insulted by a confederate who bumped into the participant and made a degrading remark. Compared with insulted participants with a weak adherence to honor norms, insulted participants with a strong adherence to honor norms were (a) more angry, (b) less joyful, (c) less fearful, and (d) less resigned. Moreover, insulted participants with a strong adherence to honor norms perceived more anger in subsequent stimuli than not-insulted participants with a strong adherence to these norms. The present findings support a direct relationship among insult, adherence to honor norms, and emotional reactions. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Nicotinamide-adenine dinucleotide phosphate oxidase assembly and activation in EBV-transformed B lymphoblastoid cell lines of normal and chronic granulomatous disease patients

This paper deals with the mechanisms of activation of NADPH oxidase investigated using EBV-transformed human B lymphoblastoid cell lines (B cells) from normal subjects and from patients affected by X-linked chronic granulomatous disease (CGD). The results reported are as follows. 1) In normal B cells, the NADPH oxidase components p67phox, p40phox, p22phox, and gp91phox were less expressed than in polymorphonuclear neutrophils. 2) In normal B cells stimulated with PMA, p47phox, p67phox, and p40phox translocated to the membranes as occurs in polymorphonuclear neutrophils. 3) In CGD, B cells expressing p22phox in the absence of gp91phox, p47phox, p67phox, and p40phox did not translocate to the membranes after stimulation with PMA. 4) In PMA-stimulated B cells from an X91+ CGD patient in which p22phox was normally expressed and gp91phox was present but lacked five amino acids, translocation of p47phox to the membranes was unaffected, but p67phox and p40phox were poorly translocated, and the production of O2- was greatly reduced with respect to that by normal B cells. Taken together, these findings indicate that 1) a low expression of some NADPH oxidase components may represent the molecular basis of the low production of O2- in B lymphocytes; 2) the cytosolic components of NADPH oxidase cannot bind to p22phox on the membranes in the absence of gp91phox; 3) p47phox can translocate to the membranes independently of p67phox and p40phox; and 4) gp91phox may have a role in mediating and/or stabilizing the binding of p67phox and p40phox to the membranes of activated cells.     

Analysis of flow instabilities in convex and concave floating zones heated by an equatorial ring under microgravity conditions

This analysis deals with advances in models concerning the floating zone technique as well as with novel results on the relative importance of various parameters in the crystal-growth process. The attention is focused in particular on microgravity fluid-dynamic aspects and on the effect of the volume of the liquid melt since the cylindrical configuration is expected to be only a very special case under microgravity conditions. The instability of Marangoni flow is investigated by direct three-dimensional and time-dependent simulation of the problem and parallel computations. Body-fitted curvilinear co-ordinates are adopted to handle the non-cylindrical shape. A novel realistic distribution is considered to model the surface heat flux generated by a ring heater positioned around the equatorial plane at a fixed distance from the axis of the liquid (full) zone.The fluid-dynamic environment that occurs inside the melt is very sensitive to the geometrical aspect ratio A_F (length/diameter) of the floating zone and to the volume factor S (ratio of the volume of the liquid zone and the volume of the corresponding cylindrical configuration: convex S>1, concave S<1). The role played by the geometrical constraints and degrees of freedom of the Marangoni toroidal rolls in determining the azimuthal structure and the stability of the flow field is discussed.     

Catalytic MTO-based C–H insertion reactions of hydrogen peroxide: an investigation on the polymeric support role in heterogeneous conditions

Polymer-supported methyltrioxorhenium (MTO) compounds are shown to act as efficient and selective catalysts for the oxy-functionalization of C–H bonds in representative hydrocarbon derivatives (leading to the corresponding alcohols or ketones), using H₂O₂ as oxidant. The different supports used for the heterogenation of MTO, such as poly(4-vinylpyridine), poly(4-vinylpyridine)-N-oxide and polystyrene resins, all showed different catalytic behaviour in terms of substrate conversion and product yield, depending on the experimental conditions used. It is noteworthy that the novel heterogeneous catalysts were found to be stable, it being possible to effect their recover and recycle at least five times without appreciable loss of activity.